Regioselectivity in the reactions of aryltriisopropoxytitanium with pyrimidinones was written by Rise, Frode;Undheim, Kjell. And the article was included in Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) in 1985.Synthetic Route of C4H4Cl2N2O This article mentions the following:
Complete regioselectivity was observed in the 1:1 condensation between 4-RC6H4Ti(OCHMe2)3 (R = H, Cl, OMe) and pyrimidin-2(1H)ones I (R1 = H; R2 = Me, CH2Ph, CH2OCH2Ph, CH2SC6H4Cl-4; R3 = H, Cl, Br, iodo). The new C-C bond was formed at C-4 to yield product II. Subsequent dehydrogenation with MnO2 or DDQ produced I (R1 = C6H4R). In the experiment, the researchers used many compounds, for example, 5-Chloropyrimidin-2(1H)-one hydrochloride (cas: 42748-90-3Synthetic Route of C4H4Cl2N2O).
5-Chloropyrimidin-2(1H)-one hydrochloride (cas: 42748-90-3) belongs to pyrimidine derivatives. The aromatic compound pyrimidine, and its derivatives, are ubiquitous in nature. They are found in nucleic acids, vitamins, amino acids, antibiotics, alkaloids, and a variety of toxins. Pyrimidine derivatives also play an important role in drug development, either in concert with other compounds or on their own.Synthetic Route of C4H4Cl2N2O
Referemce:
Pyrimidine | C4H4N2 – PubChem,
Pyrimidine – Wikipedia