Name: 5-Methylfuran-2(3H)-one. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 5-Methylfuran-2(3H)-one, is researched, Molecular C5H6O2, CAS is 591-12-8, about Synthesis of water-soluble, fully biobased cellulose levulinate esters through the reaction of cellulose and alpha-angelica lactone in a DBU/CO2/DMSO solvent system. Author is Pei, Min; Peng, Xinwen; Shen, Yuqing; Yang, Yunlong; Guo, Yuanlong; Zheng, Qiang; Xie, Haibo; Sun, Hui.
Cellulose esters are important cellulose derivatives with good processing ability and material properties. The design and sustainable synthesis of cellulose esters are prime research topics. Herein, cellulose levulinate esters (CLEs) with degrees of substitution (DSs) ranging from 0.15 to 2.04 were simply prepared through an atom-economic reaction between cellulose dissolved in a newly developed 1.8-diazabicyclo[5.4.0]undec-7-ene/dimethyl sulfoxide/carbon dioxide solvent system and alpha-angelica lactone, a biomass-derived and com. available platform chem., without the addition of any external catalysts or condensation reagents. The optimized reaction conditions of 120°C, 0.5 h, and a 5/1 molar ratio of alpha-angelica lactone to the hydroxyl groups in cellulose resulted in CLEs with appropriate DSs and satisfactory material properties. The structures and thermal properties of the CLEs were characterized by NMR spectroscopy, Fourier transform IR spectroscopy, differential scanning calorimetry, and thermal gravimetric anal. to develop an in-depth understanding of the correlations among the chem. structures, thermal properties, and mech. properties. A study of solubility in conventional solvents indicated that the CLEs with appropriate DSs were soluble in water, providing a green processing strategy to prepare CLE films with tensile strengths of up to 72 MPa and elongation at break values of up to 26.7%. The morphologies of the films were characterized by SEM and at. force microscopy. The cytotoxicity of the water-soluble CLEs was also evaluated in vaginal epithelial cells (VK2/E6E7) to identify the potential of the CLEs for biomedical applications.
In addition to the literature in the link below, there is a lot of literature about this compound(5-Methylfuran-2(3H)-one)Name: 5-Methylfuran-2(3H)-one, illustrating the importance and wide applicability of this compound(591-12-8).
Reference:
Pyrimidine | C4H4N2 – PubChem,
Pyrimidine – Wikipedia