Chambers, Richard D.; Musgrave, W. Kenneth R.; Wood, David E. published the artcile< Polyhaloaromatic compounds. Part 30. Eliminations of molecular nitrogen from trichloro- and perfluorotri-isopropyl-1,2,4-triazine>, Reference of 4956-05-2, the main research area is elimination nitrogen chlorotriazine fluoroisopropyltriazine; triazine chloro fluoroisopropyl nitrogen elimination.
3,5,6-Trichloro-1,2,4-triazine (I; R = Cl) with CF3CF:CF2 and KF gave 61% I [R = (CF3)2CF]. Gas-phase pyrolysis of I (R = Cl) gave CCl2:CClCN, indicating an intermediate azete. Pyrolysis of I [R = (CF3)2CF] gave a mixture of (CF3)2CFCCCF(CF3)2 (II) and (CF3)2CFCN, whereas photolysis resulted in rearrangement to the triazine III in addition to formation of II and (CF3)2CFCN via elimination of N.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) published new progress about Elimination reaction. 4956-05-2 belongs to class pyrimidines, and the molecular formula is C3H2BrN3O2, Reference of 4956-05-2.
Referemce:
Pyrimidine | C4H4N2 – PubChem,
Pyrimidine – Wikipedia