The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. Name: 5-Bromo-2-(trifluoromethyl)pyrimidine, 799557-86-1, Name is 5-Bromo-2-(trifluoromethyl)pyrimidine, SMILES is BrC1=CN=C(N=C1)C(F)(F)F, in an article , author is Villada, Juan D., once mentioned of 799557-86-1.
Synthesis, characterization, and redox potential properties of a new double-stranded Ni-bis(hydrazone)-based helicate
Herein we report the synthesis and structural characterization of a new Ni-bis(hydrazone) complex with the chemical formula formula [Ni-2(L)(2)(Cl)(2)](Cl)(2)center dot 2H(2)O = 2-(heptylthio)-4,6-bis(2-((E)-pyridin-2-ylmethylene)hydrazineyl) pyrimidine). Suitable crystals for X-ray diffraction showed the supramolecular interactions of this complex to exhibit a helical structure coordinating two Ni2+ metal ions bounded by two 2-(heptylthio)-4,6-bis(2-((E)-pyridin-2-ylmethylene)hydrazineyl)pyrimidine ligands. In addition, exploitation of the electrochemical properties by cyclic voltammetry, for this helicate, showed catalyzing ability for the reduction of H+ to H-2.
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Reference:
Pyrimidine | C4H4N2 – PubChem,
,Pyrimidine – Wikipedia