In the chemical reaction process,reaction time,type of solvent,can easily affect the result of the reaction, thereby determining the yield and properties of the reaction product.An updated downstream synthesis route of 5750-76-5 as follows., 5750-76-5
2,4,5-trichloropyrimidine (6.1 kg)To 2- (isopropylsulfonyl) aniline (950 g, 4.77 mol) and DBU (181 g, 1.19 mol, 0.25 equiv.)The mixture was stirred at 80 C. for 7.5 hours.After cooling to 25 C,n-heptane (1.9 kg) was added,The mixture was stirred for 30 minutes.Cool the mixture to -5 C.Filter and wash with n-heptane (325 g).The crude product is suspended in ethanol (4.5 kg),Stirred at 25 C. for 12 hours, then cooled to 0 C.After filtration, the crude was dried in vacuo,2,5-dichloro-N- (2- (isopropylsulfonyl) phenyl) pyrimidin-4-amine(1.07 kg, 65% yield).
The chemical industry reduces the impact on the environment during synthesis 5750-76-5, I believe this compound will play a more active role in future production and life.
Reference:
Patent; Novartis AG; Kapferer, Tobias; Gong, Baoqing; Davis, Mark Clinton; Zheng, Xuchun; (72 pag.)JP2019/196359; (2019); A;,
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