《Coordination Polymers from Functionalized Bipyrimidine Ligands and Silver(I) Salts》 was written by Beaulieu-Houle, Guillaume; White, Nicholas G.; MacLachlan, Mark J.. Formula: C9H6N4O2 And the article was included in Crystal Growth & Design on April 4 ,2018. The article conveys some information:
Readily functionalizable bipyrimidine compounds were prepared for the first time, and their coordination chem. with silver salts was explored. Solution 1H NMR spectroscopy experiments indicated that the ligands rapidly form complexes with silver(I) salts, and coordination at a first site inhibits coordination of a second cation to the ligand, thus favoring 1:1 complexes in solution These 1:1 units self-assemble into one-dimensional chains in the solid state, even in the presence of excess Ag(I). Structurally diverse coordination polymers exhibiting different coordination numbers and geometry were characterized by single crystal X-ray crystallog. Our results demonstrate that a modification to the ligand, distal from the binding site, affects the coordination chem. and supramol. structure of these complexes. The results came from multiple reactions, including the reaction of 2-(Pyrimidin-2-yl)pyrimidine-5-carboxylic acid(cas: 933191-25-4Formula: C9H6N4O2)
2-(Pyrimidin-2-yl)pyrimidine-5-carboxylic acid(cas: 933191-25-4) belongs to pyrimidine. Pyrimidine nucleotide derivatives have a wide range of biological applications. For example, pyrimidine derivatives are useful in DNA repair studies involving cancer and epigenetics. Formula: C9H6N4O2
Referemce:
Pyrimidine | C4H4N2 – PubChem,
Pyrimidine – Wikipedia