Feher, Csaba published the artcileSynthesis of ferrocene-labeled 2-aminopyrimidine derivatives via homogeneous catalytic carbonylation, Related Products of pyrimidines, the main research area is carbonylation iodoferrocene aminopyrimidine palladium catalyst; crystal structure mol ferrocenyl aminopyrimidine derivative preparation hydrogen bond.
The palladium-catalyzed carbonylation of iodoferrocene was investigated in the presence of 2-aminopyrimidine derivatives as nucleophiles. 2-Amino-4-hydroxy-6-methylpyrimidine was found to act both as an O- and an N-nucleophile, leading to an ester and an amide derivative, resp. Together with other spectroscopic methods, the structure of both products was proved by x-ray crystallog. 2-(Ferrocenoylamino)-4-chloro-6-alkylpyrimidines were obtained during carbonylation of iodoferrocene and 2-amino-4-chloro-6-alkylpyrimidines. The formation of a dimeric product via two subsequent carbonylation steps was also observed The products may have practical importance as electrochem. detectable biosensors or building blocks for supramol. assemblies.
Monatshefte fuer Chemie published new progress about Carbonylation. 73576-33-7 belongs to class pyrimidines, name is 4-Chloro-6-isopropylpyrimidin-2-amine, and the molecular formula is C7H10ClN3, Related Products of pyrimidines.
Referemce:
Pyrimidine | C4H4N2 – PubChem,
Pyrimidine – Wikipedia