Hou, Gui-Ge; Zhao, Hui-Juan; Sun, Ju-Feng; Lin, Dong; Dai, Xian-Ping; Han, Jing-Tian; Zhao, Hui published an article in 2013, the title of the article was Synthesis, structure and luminescence of Co-crystals with hexagonal channels: arranging disposition and π-π interactions.Synthetic Route of 160377-42-4 And the article contains the following content:
Co-crystallization of asym. building blocks 5-(4-pyridyl)pyrimidine (A) and 5-(4-(1-imidazolyl)phenyl)pyrimidine (B) with resorcinol and hydroquinone, resp., was studied. Four new organic co-crystals (1-4) were generated. The x-ray single crystal anal. indicates that the crystal packing in 1, 2 and 4 generates open hexagonal channels with resorcinol or hydroquinone mols. encapsulated through hydrogen bonding interactions. In 3, {B2(resorcinol)2} macrocycle is generated from clip-like resorcinol and asym. B mols. The luminescent properties of A, B and 1-4 were studied primarily in the solid state. The luminescent property is dependent on the mol. vertical arranging disposition and the intermol. π-π contacting characteristic. The results display more interesting tunability of the emission intensity of the building modules by the incorporation of coformers into the co-crystals. The experimental process involved the reaction of 5-(4-Bromophenyl)pyrimidine(cas: 160377-42-4).Synthetic Route of 160377-42-4
The Article related to preparation structure luminescence cobalt crystal hexagonal arranging disposition, Physical Organic Chemistry: Acid-Base, Tautomerism, and Other Equilibrium Studies and other aspects.Synthetic Route of 160377-42-4
Referemce:
Pyrimidine | C4H4N2 – PubChem,
Pyrimidine – Wikipedia