Ivanovskaya, L. Yu.; Derendyaev, B. G.; Baram, S. G. published an article on February 28 ,1982. The article was titled 《Mass spectra of pyrimidine derivatives. V. Methoxy- and dimethylaminopyrimidines》, and you may find the article in Izvestiya Sibirskogo Otdeleniya Akademii Nauk SSSR, Seriya Khimicheskikh Nauk.Name: 2-Methoxy-5-nitropyrimidine The information in the text is summarized as follows:
The mass spectra of I (R = H, F, Cl), II (R = H, F; R1 = H, F, Cl), III, IV (R = F, Cl), V, and VI (R = H, Cl; R1 = H, Me, MeO, F, Cl, NO2) were analyzed. In the case of VI (R = H), electron-donating R1 substituents favored cleavage of a C-H bond in the OMe group, whereas electron-withdrawing R1 favored loss of CH2O. The experimental part of the paper was very detailed, including the reaction process of 2-Methoxy-5-nitropyrimidine(cas: 14001-69-5Name: 2-Methoxy-5-nitropyrimidine)
2-Methoxy-5-nitropyrimidine(cas: 14001-69-5) is a member of ether. Friedel Crafts reaction, for example, adds an alkyl or acyl group to aromatic ethers when they react with an alkyl or acyl halide in the presence of a Lewis acid as a catalyst.Name: 2-Methoxy-5-nitropyrimidine
Referemce:
Pyrimidine | C4H4N2 – PubChem,
Pyrimidine – Wikipedia