Khake, Shrikant M. team published research in ACS Catalysis in 2021 | 1722-12-9

Related Products of 1722-12-9, 2-Chloropyrimidine is a monochlorinated pyrimidine with plant growth regulating activity. Chloropyrimidine is a useful reagent in the preparation of antivirals and other biologically active compounds.
2-Chloropyrimidine undergoes cobalt-catalyzed cross-coupling reaction with aryl halides.
2-Chloropyrimidine is a molecule that can be synthesized by the oxidation of pyrimidine with hydrogen peroxide and hydrochloric acid. The reaction proceeds through an electrochemical process in which the oxidation catalyst is a platinum electrode. This reaction is catalyzed by the nucleophilic attack of malonic acid on the chloropyrimidine at the methylene group. This efficient method for making 2-chloropyrimidine has been applied to synthesize aryl halides, including phenyl chloropyrimidine and pyridyl chloropyrimidine, from their corresponding chloride and bromide precursors. The fluorescence properties of 2-chloropyrimidine have been studied in coordination chemistry, where it forms complexes with metal ions such as Mn2+. In this study, it was found that adsorption mechanisms are dependent on molecular size, charge density, kinetic energy, and adsorbent surface area., 1722-12-9.

The pyrimidine ring system has wide occurrence in nature as substituted and ring fused compounds and derivatives, 1722-12-9, formula is C4H3ClN2, Name is 2-Chloropyrimidine. including the nucleotides cytosine, thymine and uracil, thiamine (vitamin B1) and alloxan. Related Products of 1722-12-9.

Khake, Shrikant M.;Yamazaki, Ken;Ano, Yusuke;Chatani, Naoto research published 《 Iridium(III)-Catalyzed Branch-Selective C-H Alkenylation of Aniline Derivatives with Alkenes》, the research content is summarized as follows. A Ir(III)-catalyzed branch-selective C-H alkenylation of aniline derivatives containing a pyrimidine-directing group with vinylsilanes and terminal aliphatic alkenes to obtain N-(2-(1-(silyl)vinyl)phenyl)pyrimidin-2-amines I [R = Me, Et, OTMs; R1 = Me, Et, OTMs; R2 = Me, Et, Ph; R3 = H, 2-Me, 2,3-(Me)2, etc.] and N-(2-(alkenyl)-methylphenyl)pyrimidin-2-amines II [R4 = n-Bu, tBu, Cy, etc.] was reported. The reaction provided a broad substrate scope for aniline derivatives, and a variety of functional groups are tolerated. D. functional theory calculations were performed in an attempt to understand the origin of the branch selectivity.

Related Products of 1722-12-9, 2-Chloropyrimidine is a monochlorinated pyrimidine with plant growth regulating activity. Chloropyrimidine is a useful reagent in the preparation of antivirals and other biologically active compounds.
2-Chloropyrimidine undergoes cobalt-catalyzed cross-coupling reaction with aryl halides.
2-Chloropyrimidine is a molecule that can be synthesized by the oxidation of pyrimidine with hydrogen peroxide and hydrochloric acid. The reaction proceeds through an electrochemical process in which the oxidation catalyst is a platinum electrode. This reaction is catalyzed by the nucleophilic attack of malonic acid on the chloropyrimidine at the methylene group. This efficient method for making 2-chloropyrimidine has been applied to synthesize aryl halides, including phenyl chloropyrimidine and pyridyl chloropyrimidine, from their corresponding chloride and bromide precursors. The fluorescence properties of 2-chloropyrimidine have been studied in coordination chemistry, where it forms complexes with metal ions such as Mn2+. In this study, it was found that adsorption mechanisms are dependent on molecular size, charge density, kinetic energy, and adsorbent surface area., 1722-12-9.

Referemce:
Pyrimidine | C4H4N2 – PubChem,
Pyrimidine – Wikipedia