Prier, Christopher K.; MacMillan, David W. C. published the artcile< Amine α-heteroarylation via photoredox catalysis: a homolytic aromatic substitution pathway>, Related Products of 89793-12-4, the main research area is alpha heteroaryl amine regioselective preparation photoredox; tertiary amine heteroarene heteroarylation iridium.
The direct α-heteroarylation of tertiary amines has been accomplished via photoredox catalysis to generate valuable benzylic amine pharmacophores. A variety of five- and six-membered chloroheteroarenes are shown to function as viable coupling partners for the α-arylation of a diverse range of cyclic and acyclic amines. Evidence is provided for a homolytic aromatic substitution mechanism, in which a catalytically-generated α-amino radical undergoes direct addition to an electrophilic chloroarene.
Chemical Science published new progress about Aromatic heterocyclic amines Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation) (α-). 89793-12-4 belongs to class pyrimidines, and the molecular formula is C7H7ClN2O2, Related Products of 89793-12-4.
Referemce:
Pyrimidine | C4H4N2 – PubChem,
Pyrimidine – Wikipedia