Sakamoto, Takao published the artcileStudies on pyrimidine derivatives. XVI. Site selectivity in the homolytic substitution of simple pyrimidines, Recommanded Product: 1-(6-Methylpyrimidin-4-yl)ethanone, the main research area is substitution homolytic pyrimidine; acylation pyrimidine homolytic; hydroxymethylation pyrimidine homolytic; oxidation methylpyrimindine; crosscoupling reaction methylpyrimidine; coupling reaction methylpyrimidine cross; amidation methylpyrimidine; ethoxycarbonylation methylpyrimidine; ketone pyrimidine; amide pyrimidine.
Pyrimidines in which both the 2- and 4-positions are free showed site selectivity in their reactions with radicals generated in redox systems. Thus treating 6-phenyl- (I), 6-methylpyrimidine, and 5,6,7,8-tetrahydroquinazoline with radicals, e.g. RC•O, R2NC•O, EtO2C•, •CH2OH, gave predominantly the 4-substituted products. Only the reaction of I with Me2NC•O gave any 2-substituted products.
Chemical & Pharmaceutical Bulletin published new progress about Cross-coupling reaction. 67073-96-5 belongs to class pyrimidines, name is 1-(6-Methylpyrimidin-4-yl)ethanone, and the molecular formula is C7H8N2O, Recommanded Product: 1-(6-Methylpyrimidin-4-yl)ethanone.
Referemce:
Pyrimidine | C4H4N2 – PubChem,
Pyrimidine – Wikipedia