Seela, Frank; Soulimane, Tewfik; Mersmann, Karin; Juergens, Thomas published the artcile< 2,4-Disubstituted pyrrolo[2,3-d]pyrimidine α-D- and β-D-ribofuranosides related to 7-deazaguanosine>, Recommanded Product: 4-Methoxy-7H-pyrrolo[2,3-d]pyrimidin-2-amine, the main research area is pyrrolopyrimidine stereoselective glycosidation ribofuranosyl chloride; deazaguanosine related pyrrolopyrimidine ribofuranoside; guanosine deaza related pyrrolopyrimidine ribofuranoside; nucleoside.
Nucleobase-anion glycosylation [KOH, (MeOCH2CH2OCH2CH2)3N] of the pyrrolo[2,3-d]pyrimidines I (R = Cl, OMe, R1 = NH2, SMe) with ribofuranosyl chlorides gave the corresponding protected β-D-nucleosides stereoselectively. Contrary, II (R2 = Cl, R3 = H) yielded the corresponding α-D-nucleosides apart from minor amounts of the β-D-anomers. The deprotected nucleosides III (R4 = Cl) were converted into 4-substituted 2-aminopyrrolo[2,3-d]-pyrimidine β-D-ribofuranosides e.g. III (R4 = H, NH2, OMe), and into their α-D-anomers, resp.
Helvetica Chimica Acta published new progress about Glycosylation, stereoselective. 84955-32-8 belongs to class pyrimidines, and the molecular formula is C7H8N4O, Recommanded Product: 4-Methoxy-7H-pyrrolo[2,3-d]pyrimidin-2-amine.
Referemce:
Pyrimidine | C4H4N2 – PubChem,
Pyrimidine – Wikipedia