Chemistry, like all the natural sciences, Computed Properties of C4H2BrFN2, begins with the direct observation of nature¡ª in this case, of matter.947533-45-1, Name is 2-bromo-5-fluoropyrimidine, SMILES is FC1=CN=C(Br)N=C1, belongs to pyrimidines compound. In a document, author is Liu, Yang, introduce the new discover.
A 3D Adenine-based Cd-MOF: Synthesis, Structure and Photoluminescent Sensing for an Aromatic Azo Compound
A new Cd-MOF containing the nucleobase adenine and multicarboxylates, Cd-2(tdc)(2)(1H-ade)(2)(H2O) (H(2)tdc = 2,5-thiophene carboxylic acid, 1H-ade = adenine), was synthesized successfully under hydrothermal condition and characterized by single-crystal X-ray diffraction, infrared spectrum, thermogravimetric analysis and photoluminescence. The two crystallographically unsymmetrical Cd atoms are bridged by 2,5-tdc ligands with (kappa(1)-kappa(1))-(kappa(1))-mu(3) and (kappa(1)-kappa(1))-mu(2) modes into two dimensional extended layers, which are further pillared with the neutral ade molecules to form a 3D frameworks stabilized by extensive pi center dot center dot center dot pi interactions between imidazole-, pyrimidine- and thiophene-rings. Inspection of the structure reveals that the architecture can be simplified as a 3,4,5- connected networks with a Schlafli symbol of (6(2)center dot 8)(4(2)center dot 6(3)center dot 8)(4(2)center dot 6(5)center dot 8(3)). The photochemical property shows that the luminescent emission can be significantly quenched by aromatic azo compounds. The quenching effect coefficient (K-sv) for bis(4-imidazol-1-yl-phenyl)diazene is determined to be 4.1 x 10(4) m(-1), indicating the title compound as a potential fluorescent sensing materials.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 947533-45-1. Computed Properties of C4H2BrFN2.
Reference:
Pyrimidine | C4H4N2 – PubChem,
,Pyrimidine – Wikipedia