Van der Does, L. published the artcileDerivatives of pyrimidine. XXVII. Bromination of pyrimidine in the gas phase, Safety of 2,4,6-Tribromopyrimidine, the main research area is bromination pyrimidine gas phase; bromopyrimidine; aminopyrimidine.
The gas-phase bromination of pyrimidine gives 5-bromo-, 4,6-dibromo-, 2,4,6-tribromo- and 4-aminopyrimidine depending on the temperature and presence of a contact substance. Thus, pyrolysis of pyrimidine-Br at 220° gave 5% 5-bromopyrimidine and 40% 4-aminopyrimidine, whereas at 220° with pumice, only 60% 5-bromopyrimidine was found. Empty-tube pyrolysis gave Br attack at the pos.-charged positions, whereas the presence of pumice caused attack at C-5, the least-charged position.
Tetrahedron Letters published new progress about Bromination. 36847-11-7 belongs to class pyrimidines, name is 2,4,6-Tribromopyrimidine, and the molecular formula is C4HBr3N2, Safety of 2,4,6-Tribromopyrimidine.
Referemce:
Pyrimidine | C4H4N2 – PubChem,
Pyrimidine – Wikipedia